what is PHPA polymer and what is the main applicaitons in oilfeild? - CHINAFLOC
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what is PHPA polymer and what is the main applicaitons in oilfeild?
2023-11-09 09:46:31

what is PHPA polymer and what is the main applicaitons in oilfeild?


Partially Hydrolyzed Polyacrylamide (PHPA) is a polymer derived from acrylamide, a water-soluble monomer. It undergoes partial hydrolysis to enhance its performance in various applications, including the oilfield industry. PHPA polymers have a wide range of applications due to their unique properties, such as high water solubility, flocculation capabilities, and viscosity control. In the oilfield, PHPA finds extensive use in diverse processes aimed at improving oil recovery and enhancing drilling operations.

Chemical Structure and Properties of PHPA:

PHPA is a synthetic polymer with repeating acrylamide units. The partial hydrolysis of acrylamide introduces carboxyl groups into the polymer chain, enhancing its water solubility and other characteristics. The resulting polymer has both hydrophilic and hydrophobic segments, allowing it to interact effectively with water and oil.

Oilfield Applications of PHPA:

1. Enhanced Oil Recovery (EOR):

PHPA plays a crucial role in Enhanced Oil Recovery (EOR) processes. In primary and secondary recovery stages, not all oil can be extracted from reservoirs. EOR techniques, including polymer flooding, aim to improve oil displacement by altering the properties of injected water. PHPA, when added to the injection water, increases its viscosity. The higher viscosity improves the water's ability to sweep through the reservoir, pushing more oil towards production wells. This process is particularly effective in reservoirs with high permeability contrast or where water mobility is an issue.

2. Drilling Fluids:

PHPA is a key component in drilling fluids, which are essential for drilling oil and gas wells. Drilling fluids, also known as drilling muds, serve multiple purposes, including cooling the drill bit, carrying drill cuttings to the surface, and providing wellbore stability. PHPA is added to drilling fluids to control their rheological properties. It enhances viscosity, reduces friction, and improves the carrying capacity of the fluid. These properties are crucial for effective drilling in various geological formations.

3. Fracturing Fluids in Hydraulic Fracturing:

In hydraulic fracturing, or fracking, PHPA is used as a friction reducer and viscosifier in the fracturing fluid. The fracturing fluid is pumped into the wellbore at high pressure to create fractures in the rock formation, allowing for the extraction of oil and gas. PHPA helps in maintaining the viscosity of the fluid, ensuring efficient fracturing and preventing proppant settling.

4. Well Stimulation:

PHPA is employed in well stimulation treatments to improve the performance of the well. It helps in controlling fluid loss, reducing water production, and improving the overall efficiency of stimulation fluids. This is particularly important in reservoirs where water influx can impact production rates and recovery efficiency.

5. Water Shutoff in Mature Fields:

In mature oilfields, water breakthrough is a common issue, where water displaces oil, leading to decreased production. PHPA can be used to control water production by selectively blocking water-producing zones. This process, known as water shutoff, involves injecting PHPA into the water-producing zones to reduce their permeability and restrict water flow.

6. Clay Stabilization:

PHPA is utilized for clay stabilization in drilling operations. Clays present in the formation can swell and cause wellbore instability. The addition of PHPA helps in preventing clay swelling and improves the overall stability of the wellbore.

Challenges and Considerations:

While PHPA offers numerous benefits in oilfield applications, it's important to consider potential challenges. The cost of PHPA and the environmental impact of its use are factors that operators must weigh against the economic benefits of improved oil recovery.


Partially Hydrolyzed Polyacrylamide (PHPA) polymers play a pivotal role in enhancing oil recovery and optimizing drilling operations in the oilfield industry. With their versatile properties, PHPA polymers contribute to improved water and oil displacement, reduced friction in drilling fluids, and enhanced recovery from mature fields. As the oil and gas industry continues to evolve, PHPA and similar polymers will likely remain integral to the development and implementation of advanced technologies aimed at maximizing hydrocarbon recovery.